Crystal structure, thermal analysis and IR spectroscopic investigation of bis (N-methyl anilinium) sulfate
Crystal structure, thermal analysis and IR spectroscopic investigation of bis (N-methyl anilinium) sulfate作者机构：不详
出 版 物：《Open Journal of Inorganic Chemistry》 (无机化学期刊（英文）)
年 卷 期：2011年第1卷第3期
页 面：47-53页
主 题：Chemical Preparation Crystal Structure Thermal Behavior Organic Sulfate Infrared Spectroscopy
摘 要：Chemical preparation, X-ray single crystal, thermal analysis and IR spectroscopic investigation of (C7H10N)2 SO4 denoted NMAS are described. The NMAS crystallizes in the triclinic system with P-1 space group. Its unit cell dimensions are a = 9.6150(5) ?, b = 9.9744(3) ?, c = 10.2767(6) ?, α = 68.069(3)°, β = 62.929(2)°, γ = 67.285(3)° with V = 785.72(7) ?3 and Z = 2. The structure has been solved using direct method and refined to a reliability R factor of 3.62%. The NMAS structure is built up from chains containing all the components of the structure and parallel to the b axis, linked via N—H-----···O hydrogen bonds. Stability between successive chains is performed by weak interactions originating from the organic cations.
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