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Effect of copper impurity on the optical loss and Nd^(3+) nonradiative energy loss of Nd-doped phosphate laser glass

Effect of copper impurity on the optical loss and Nd^(3+) nonradiative energy loss of Nd-doped phosphate laser glass

作     者:徐永春 李顺光 胡丽丽 陈伟 

作者机构:Shanghai Institute of Optics & Fine Mechanics Chinese Academy of Sciences 

出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))

年 卷 期:2011年第29卷第6期

页      面:614-617页

核心收录:

学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

主  题:Nd-doped phosphate laser glass optical loss nonradiative energy loss Cu impurity rare earths 

摘      要:N31-type phosphate laser glasses doped with different concentrations of Cu were prepared. Their optical loss coefficient at 1053 nm wavelength and nonradiative transition rate from the Nd3+ 4F3/2 state were determined and analyzed in detail. The optical loss coefficient per unit of Cu2+ (cm–1/ppmw) and the fluorescence decay rate (Hz/ppmw) caused by Cu2+ and Nd3+ interaction were 0.0024 and 7.9, respectively. Cu impurity affected both optical loss at 1053 nm and fluorescent emission of Nd3+ 4F3/2 state seriously in N31 laser glass.

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