On-line batch production of ferrate with an chemical method and its potential application for greywater recycling with Al(Ⅲ) salt

作     者：Yarui Song Bin Men Dongsheng Wang Jianwei Ma 

作者机构：Northeast Petroleum University Institute of Civil Engineering and Construction State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2017年第29卷第2期

页      面：1-7页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.41201498,51338010,51290282) the National Water Pollution Control and Treatment Science and Technology Major Project(No.2015ZX07205-003) 

主　　题：On-line Ferrate Coagulation Oxidation Greywater AlCl3 

摘      要：Ferrate（Ⅵ ） salt is an oxidant and coagulant for water and wastewater treatment. It is considered as a possible alternative method in greywater treatment. However, challenges have existed in putting ferrate（Ⅵ ） technology into full-scale practice in water and wastewater treatment due to the instability of ferrate solution and high production cost of solid ferrate products. This study demonstrated a new approach of greywater treatment with on-line batch production of Fe（Ⅵ ） to which Fe（Ⅲ ） salt was oxidized at a weak acidity solution. A series of experiments were conducted to investigate the effect of Fe（Ⅵ ） on light greywater（total organic carbon（TOC） = 19.5 mg/L） and dark greywater（TOC = 55 mg/L）treatment under different conditions with varying p H and Fe（Ⅵ ） doses. In addition, the combination use of Fe（Ⅵ ） and Al（Ⅲ ） salts was proved to be more efficient than using the Fe（Ⅵ ） salts alone at greywater recycling. The optimum dosage of Fe（Ⅵ ）/Al（Ⅲ ） salts was 25/25 mg/L for light greywater, 90/60 mg/L for dark greywater, respectively. The TOC values of both light greywater and dark greywater were reduced to less than 3 mg/L with the *** cost for treating greywater was 0.06–0.2 $/ton at ferrate（Ⅵ ） dosage of 25–90 mg/L and0.008–0.024 $/ton at AlCl3 dosage of 25–60 mg/L. The full operating cost needs further assessment before the Fe（Ⅵ ）/Al（Ⅲ ） technology could be implemented in greywater treatment.