NARROW-DISPERSED CROSSLINKED CORE-SHELL POLYMER MICROSPHERES PREPARED BY SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION

作     者：Yu-zengZhao Xin-linYang FengBai 黄文强 

作者机构：StateKeyLaboratoryofFunctionalPolymerMaterialsforAdsorptionandSeparationInstituteofPolymerChemistryNankaiUniversityTianjin300071China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2005年第23卷第3期

页      面：293-299页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(No.20274018) 

主　　题：Atom transfer radical polymerization(ATRP) Core-shell polymers Grafting polymerization Surface-initiated polymerization. 

摘      要：Grafting of polystyrene with narrowly dispersed polymer microspheres through surface-initiated atom transferradical polymerization(ATRP)was ***(PDVB)microspheres were prepared by dispersionpolymerization with poly(N-vinyl pyrrolidone)(PVP)as *** surfaces of PDVB microspheres werechloromethylated by chloromethyl methyl ether in the presence of zinc chloride as catalyst to form chloromethylbenzeneinitiating core sites for subsequent ATRP grafting of styrene using CuCl/bpy as catalytic *** was found to begrafted not only from the particle surfaces but also from within a thin shell layer,resulting in the formation of particles sizeincreased from 2.38-2.58 μm,which can further grow to 2.93 μm during secondary grafting polymerization of *** that grafting polymerization proceeds through a typical ATRP procedure with living *** of the preparedmicrospheres have narrow particle size distribution with coefficient of variation around 10%.