Tf_2NH-catalyzed,highly regio-and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes

作     者：Hai-Hua Li 

作者机构：Department of Environmental and Chemical EngineeringTangshan College 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2015年第26卷第3期

页      面：320-322页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：alcohols catalyzed afford selectivity stereo Friedel react catalysis inexpensive stilbene 

摘      要：A reaction of benzylic alcohols with alkenes has been developed in the presence of bis（trifluoromethane）sulfonimide for the synthesis of trisubstituted alkenes and indane derivatives with high *** general,benzylic alcohols react with 1,1-diaryl alkenes to afford trisubstituted alkenes,and the reaction with 1,2-disubstituted and trisubstituted alkenes affords indane derivatives through a [3 ＋ 2] annulation reaction.