In Situ Synthesis of Block Copolymer Nano-assemblies by Polymerization- induced Self-assembly under Heterogeneous Condition

作     者：Sheng-li Chen Peng-fei Shi 张望清 

作者机构：Key Laboratory of Functional Polymer Materials of the Ministry of EducationInstitute of Polymer ChemistryNankai University Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Nankai University 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2017年第35卷第4期

页      面：455-455,456-479页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：financially supported by the National Science Foundation for Distinguished Young Scholars(No.21525419) the National Natural Science Foundation of China(Nos.21274066 and 21474054) the National Key Research and Development Program of China(No.2016YFA0202503) 

主　　题：Block copolymers Self-assembly Emulsion RAFT polymerization Dispersion RAFT polymerization SeededRAFT polymerization 

摘      要：Controlled synthesis of amphiphilic block copolymer nanoparticles in a convenient way is an important and interest topic in polymer science. In this review, three formulations of polymerization-induced self-assembly to in situ synthesize block copolymer nanoparticles are briefly introduced, which perform by reversible addition-fragmentation chain transfer （RAFT） polymerization under heterogeneous conditions, e.g., aqueous emulsion RAFT polymerization, dispersion RAFT polymerization and especially the recently proposed seeded RAFT polymerization. The latest developments in several selected areas on the synthesis of block copolymer nano-assemblies are highlighted.