CO and C_3H_8 total oxidation over Pd/La-Al_2O_3 catalysts: Effect of calcination temperature and hydrothermal treatment

作     者：周仁美 邢丰 王树元 鲁继青 金凌云 罗孟飞 ZHOU Renmei;XING Feng;WANG Shuyuan;LU Jiqing;JIN Lingyun;LUO Mengfei

作者机构：Key Laboratory of the Ministry of Education for Advanced Catalysis MaterialsInstitute of Physical ChemistryZhejiang Normal University 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2014年第32卷第7期

页      面：621-627页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：Project supported by National Natural Science Foundation of China(21173195 21203167) 

主　　题：Pd/La-Al2O3catalysts stability turnover frequencies hydrothermal ageing rare earths 

摘      要：A series of Pd/La-Al2O3（PLA） catalysts with La-Al2O3（LA） support calcined at different temperatures（500, 700, 900 and 1050 oC） were prepared using an incipient wetness impregnation method. The activity of the fresh and hydrothermally aged PLA catalysts were tested for total oxidation of CO and C3H8. The activity of the fresh PLA catalysts for CO and C3H8 oxidation increased with increasing calcination temperature of the support, while the activities of the aged catalysts declined and became essentially the same. CO chemisorption results revealed that the suppressed activities of the aged catalysts were mainly due to the decline of palladium dispersion. The turnover frequency（TOF） of CO oxidation increased with increasing reduction ability of the catalysts, with a fresh catalyst calcined at 1050 oC having the highest value（0.048 s–1）. However, the TOF of C3H8 total oxidation was affected by not only the redox properties of catalysts but also the size of Pd particle, and large Pd particles possessed higher TOF value of C3H8 oxidation, with the highest value（0.125 s–1） being obtained on an aged catalyst calcined at 500 oC.