Thermodynamic Study on the Rare Earth Vapour Complex PrAl_3Cl_(12)

作     者：王林山 高荣杰 苏轶 王之昌 

作者机构：Department of Chemistry Northeastern University Shenyang 110006 China 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：1997年第15卷第2期

页      面：28-33页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

主　　题：Rare earths PrCl 3 AlCl 3 Vapour complex Quenching Thermodynamics 

摘      要：Thermodynamic study on the reaction PrCl 3(s) +( x /2) Al 2Cl 6(g) =PrAl x Cl 3 x +3(g) was carried out by quenching experiments within 604～827 K and 0 05～0 15 MPa. The results suggested that the PrAl 3Cl 12(g) complex was the predominant species. The equilibrium constants of the reaction were measured. The reaction enthalpy and entropy derived from the measurements were ΔH 0 298 =(38 2±2) kJ·mol -1 and ΔS 0 298 =(1 2±3) J·mol -1 ·K -1 .