KINETICS AND MECHANISM OF REACTIONS OF Bis(N, N-DIETHYLDITHIOCARBAMATO)ALKYLXANTHATOCOBALT(Ⅲ) WITH DIETHYLAMINE IN METHANOL

作     者：王安周 单金缓 霍守钦 

作者机构：Department of Chemistry Hebei University Baoding 

出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期：1989年第34卷第3期

页      面：261-263页

核心收录：

学科分类：07[理学] 08[工学] 

主　　题：hereafter methanol letter ternary abbreviated kinetics complexes coordinated substitution referred 

摘      要：Studies on the substitution reactions occurring on a coordinated ligand of ternary complexes are rarely reported so far. In this letter we are reporting our study on the kinetics of the reactions of ternary complexes, Co（S2CNEt2）2（S2COR） （abbreviated to t-complex hereafter, R=Me, Et, n-Pr）, with diethylamine NHEt2 in methanol medium in a temperature range of 20--40℃. All of the solutions referred to below are methanol （A. R.） solutions.