Effects of W and Mo Additions on Wet-dry Acid Corrosion Behavior of Low-Alloy Steels Under Different O_2 Concentrations

作     者：Qing-He Zhao Wei Liu Shuan-Zhu Li Bin-Li Zhang Yi-Chun Zhu Min-Xu Lu 

作者机构：Corrosion and Protection Center Institute for Advanced Materials and Technology University of Science and Technology Beijing 

出 版 物：《Acta Metallurgica Sinica(English Letters)》 (金属学报（英文版）)

年 卷 期：2016年第29卷第10期

页      面：951-962页

核心收录：

学科分类：0817[工学-化学工程与技术] 0806[工学-冶金工程] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0802[工学-机械工程] 0703[理学-化学] 0811[工学-控制科学与工程] 

基　　金：financially supported by the National Natural Science Foundation of China (No. 51571027) 

主　　题：Wet-dry acid corrosion Steel Corrosion resistance Electrochemical impedance spectroscopy(EIS) Rust 

摘      要：Effects of W and Mo additions on wet-dry acid corrosion behavior of low-alloy steels under different O2 concentrations were investigated. The results showed that W and Mo-containing steels presented excellent wet-dry cor- rosion resistance under O2 concentrations of both 1 and 5%. The roles of W and Mo played in increasing corrosion resistance of the steels were different. W could improve the thermodynamic stability of the steel substrate, while Mo could promote the formation of protective rust. Interaction between W, Mo and O2 concentration greatly influenced wet-dry acid corrosion of low-alloy steels. W addition was more effective for depressing charge transfer process at the rust/substrate interface and presented higher enhanced effect on increasing corrosion resistance than Mo under O2 concentration of 1%. Mo was more effective on increasing rust compactness and showed higher enhanced effect on increasing corrosion resistance than W under O2 concentration of 5%.