Synthesis and Characterization of S,N-Heteroacenes by Bischler-Napieralski Reaction

作     者：Hong-shuang Guo Mei-fang Liu Yi Han 韩生 陈于蓝 

作者机构：School of Chemical and Environmental Engineering Shanghai Institute of Technology Shanghai 201418 China Tianjin Key Laboratory of Molecular Optoelectronic Science Tianjin University Tianjin 300072 China Department of Chemistry Weifang University Weifang 261061 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2016年第34卷第11期

页      面：1319-1329页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(Nos.51503142,21522405 and 20976105) Shanghai Leading Academic Discipline Project(No.J51503) Shanghai Municipal Education Commission Boosting Project(No.15cxy39) the Open Project of the State Key Laboratory of Supramolecular Structure and Materials(No.SKLSSM201505) 

主　　题：solubility conjugated fused cyclization prepare packing chloroform dilute analogue diamine 

摘      要：Bischler-Napieralski cyclization has been successfully employed to prepare planar S,N-heteroacenes（SNHs） with the analogue structures to 1,10-phenanthroline. The opto-/electrical properties and the packing modes of these S,Nheteroacenes were examined, which were dependent on the structure of the fused groups. SNH-based copolymers with high molecular weight and good solubility in common organic solvents or water have been synthesized by Suzuki-MiyauraSchlüter polycondensation. The photophysical property studies revealed that the copolymers may be a promising chemosensor material.