CRYSTAL STRUCTURES OF 1,2-BENZO[2.2]PARACYCLOPHANE AND 1,2-BENZO[2.2]PARACYCLOPHANE-1,7-DIENE

作     者：黄乃正 陈展榮 麥松威 Henry N.C.Wong Chin Wing ChanThomas C.W. MakDepartment of Chemistry, The Chinese University of Hong Kong,Shatin, New Territories, Hong Kong

作者机构：Department of Chemistry The Chinese University of Hong Kong Shatin New Territories Hong Kong 

出 版 物：《结构化学》 (Chinese Journal of Structural Chemistry)

年 卷 期：1985年第3期

页      面：214-217页

学科分类：07[理学] 0703[理学-化学] 

主　　题：parent orthorhombic fused substitution benzene morethan bonds diene adequately allowed 

摘      要：C20H16 (1) Mr = 256.34 and C20H14 (2), Mr = 254.32 are isomorphous, orthorhombic, P212121, Z = 4. For (?), ?a= 7.116(1), b =7.874(2), c = 24.564(4) A, V = 1376.4(3) A3, Dx = 1.237 g cm-3, μ(Mo-K α) =0.65 cm-1 , final R = 0.047 for 1152 observed reflections; for 2, a=6.963(2), b = 7.985(4), c = 24.315(8) A, V = 1351.9(8) A3, Dx = 1.250 g cm-3,μ(Mo-Kα) = 0.66 cm-1 , final R = 0.076 for 886 observed data. Structuralfeatures are similar to those of the parent [2.2]paracyclophane and related derivatives.