SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CLUSTER COMPLEX [(C_2H_5)_4N]_3[Mo_2FeS_8O_2]

作     者：徐吉庆 刘喜生 牛淑云 李淑琴 樊玉国 王风山 吕品喆 XU JIQING LIU XISHENG NIU SHUYUN LI SHUQIN (Nitrogen Fixation Research Group, Department of Chemistry, Jilin University, Changchun) FAN YUGUO WANG FENGSHAN Lü PINZHE (Institute of Theoretical Chemistry, Jilin University, Changchun)

作者机构：Nitrogen Fixation Research Group Department of Chemistry Jilin University Changchun Institute of Theoretical Chemistry Jilin University Changchun 

出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期：1984年第29卷第3期

页      面：344-347页

学科分类：07[理学] 0703[理学-化学] 

主　　题：chemically ammonia fixation molybdenum clarify simulating borate methanol turnover donor 

摘      要：Ⅰ. INTRODUCTION One of the principal aims of the chemically simulating studies of biological nitrogen fixation is the improvement of the catalyst of ammonia synthesis industrially. It will be very important for us to clarify the structure and functions of nitrogenase. Successful separation of a FeMo-co from the MoFe protein of the Azotobacter vinelandii (Az. v.) has made the studies on the active center of nitrogen fixation of nitrogenase enter a new stage. The molybdenum K-edge extended X-ray absorption fine