ROD-LIKE AGGREGATES FROM POLYSTYRENE-b-POLY(4-VINYLPYRIDINE)-b-POLYSTYRENE TRIBLOCK COPOLYMER IN AQUEOUS MEDIA

作     者：程时远 江雷 

作者机构：College of Chemistry & Materials Sciences Hubei University Wuhan 430062 China Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2004年第22卷第1期

页      面：17-23页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：Block copolymers Self-assembly Rod-like aggregates Bicontinuous Lamellae 

摘      要：The rod-like assembly from BAB block copolymer with hydrophilic middle block A in aqueous solution was described. The copolymer used is polystyrene (PS)39-b-poly(4-vinylpyridine)(P4VP)98-b-PS39 (the subscripts are the average polymerization degree of corresponding blocks) triblock copolymer with Mw/Mn = 1.15. The aggregates were characterized by transmission electron microscopy and atomic force microscopy. The dependence of rod-like aggregate formation on solvents, pH, and polymer concentrations was investigated. The rod-like aggregates were formed when using dioxane as initial solvent, while spherical micelles were formed using DMF. Elevating pH values from 4 to 5 to 7 and decreasing initial copolymer concentrations from 1.5 wt% to 1.0 wt% to 0.5 wt% were favorable for the formation of well-defined rod-like aggregates. In addition, the bicontinuous rods and lamellae were observed when preparing colloid solutions in appropriate conditions.