2D-π-A Type Organic Dyes Based on N,N-Dimethylaryl Amine and Rhodamine-3-acetic Acid for Dye-sensitized Solar Cells

作     者：Tang, Kai Liang, Mao Liu, Yongkang Sun, Zhe Xue, Song 

作者机构：Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 China Department of Applied Chemistry Tianjin University of Technology Tianjin 300384 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2011年第29卷第1期

页      面：89-96页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0803[工学-光学工程] 

基　　金：Project supported by the National 863 Program (No. 2009AA05Z421) and the Tianjin Natural Science Foundation (No. 09JCZDJC24400) 

主　　题：dye-sensitized solar cell photovoltaic N,N-dimethylaryl amine organic dyes 

摘      要：Three organic dyes XS17--19 based on N,N-dimethylaryl amine and rhodamine-3-acetic acid moieties are designed and synthesized. These dyes were applied into nanocrystalline TiOa dye-sensitized solar cells through standard operations, showing strong absorption bands at around 320--650 rim, and exhibiting broad IPCE responses. Cell based on XS17 gave a Jsc of 3.7 mA/cm2, an open circuit voltage of 550 mV, and a fill factor of 0.68, corresponding to an overall conversion efficiency of 1.4%. The low overall conversion efficiency is due to the modest IPCE and Voc values, which mainly stem from the acceptor of rhodanine-3-acetic acid.