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ELECTRORHEOLOGICAL PROPERTIES OF POLYANILINE/PUMICE COMPOSITE SUSPENSIONS

ELECTRORHEOLOGICAL PROPERTIES OF POLYANILINE/PUMICE COMPOSITE SUSPENSIONS

作     者:Mustafa Yavuz 

作者机构:Department of ChemistryFaculty of Arts and ScienceSüleyman Demirel University32260 IspartaTurkey 

出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))

年 卷 期:2007年第25卷第4期

页      面:347-355页

核心收录:

学科分类:0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 

基  金:This work was financially supported by the TUBITAK (Turkish Scientific and Technical Research Foundation) Süleyman Demirel University (Nos. TBAG-AY-344, SDU BAP 03-m-714) 

主  题:Electrorheology Yield stress Pumice Composite Suspension 

摘      要:Electrorheological (ER) properties of polyaniline (PAni), pumice and polyaniline/pumice composites (PAPC) were investigated. Polyaniline and PAni/pumice composite were prepared by oxidative polymerization. PAni/pumice particlesbased ER suspensions were prepared in silicone oil (SO), and their ER behavior was investigated as a function of shear rate, electric field strength, concentration and temperature. Sedimentation stabilities of suspensions were determined. It has been found that ER activity of all the suspensions increases with increasing electric field strength, concentration and decreasing shear rate. It has shown that the suspensions have a typical shear thinning non-Newtonian viscoelastic behavior. Yield stress of composite suspensions increased linearly with increasing applied electric field strength and with concentrations of the particles. The effect of high temperature on ER activity of purrfice/silicone oil systems was also investigated.

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