甲酸在钯微粒修饰聚苯胺电极上氧化的协同效应研究

作     者：钟起玲 熊丽华 钟志京 李五湖 

作者机构：江西师范大学化学系南昌330027 厦门大学固体表面物理化学国家重点实验室化学系厦门361005 

出 版 物：《物理化学学报》 (Acta Physico-Chimica Sinica)

年 卷 期：1996年第12卷第4期

页      面：346-352页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：国家教委基金 

主　　题：甲酸 钯 聚苯胺 协同效应 氧化 化学修饰电极 

摘      要：Electrochemical oxidation of formic acid on PAN(Pd) electrode has been studied using conventional electrochemical tecdriques and the electrochemical in-situ *** process of electrochemical oxidation of PAN(Pd) electorde has been put forward. The kinetic parameters of different thickness of PAN film such as diffision coefficient (D0) and reaction rate constant(k0) have been calculated. Furthermore, the causes of the difference between PAN(Pd) and pure Pd(or Pt) electrodes as well as the high electrocatalytic activation of PAN(Pd) electrode for oxidation of fomic acid have also been discussed. The high catalytic activation of PAN(Pd) electrode for oxidation of formic acid probably comes from the synergistic effect of the subcatalytic interaction of PAN and the catalytic interaction of the palladium microparticles.