Structure Refinement of Samarium Tritellurides
Structure Refinement of Samarium Tritellurides作者机构:StateKeyLaboratoryofStructuralChemistryFujianInst StateKeyLaboratoryofStructura
出 版 物:《Chinese Journal of Structural Chemistry》 (结构化学(英文))
年 卷 期:1996年第15卷第4期
页 面:267-269页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题:synthesis telluride crystal structure
摘 要:The title compound was prepared from the corresponding elements(Sm, Te) using iodine as transport agent. The crystal structure was determined by the single crystal X-ray diffraction techniques with the crystal data as follows: SmTe3,M_r= 533. 15, orthorhombic. Cmcm, a=4. 323(2), b= 25. 613(3),c=4. 335(2) A,V=480. 0 A ̄3, Z=4, D_x=7. 38 g/cm ̄3, F(000) =872,μ= 300. 2 cm ̄(-1), R=0. 061,Rw.=0. 066 for 660 observed(I≥3σ(I)) unique reflections. The compound is isostructural with NdTe_3 ̄[1].