Ternary compounds and solid-state phase equilibria in Mg-rich side of Mg-Zn-Ca system at 300 ℃

作     者：李洪晓 任玉平 马倩倩 蒋敏 秦高梧 LI Hong-xiao;REN Yu-ping;MA Qian-qian;JIANG Min;QIN Gao-wu

作者机构：东北大学材料各向异性与织构教育部重点实验室沈阳110819 

出 版 物：《Transactions of Nonferrous Metals Society of China》 (中国有色金属学报（英文版）)

年 卷 期：2011年第21卷第10期

页      面：2147-2153页

核心收录：

学科分类：0806[工学-冶金工程] 08[工学] 0818[工学-地质资源与地质工程] 0815[工学-水利工程] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0813[工学-建筑学] 0703[理学-化学] 0814[工学-土木工程] 0702[理学-物理学] 

基　　金：Project(50731002) supported by the National Natural Science Foundation of China Project(20082030) supported by the Natural Science Foundation of Liaoning Province,China 

主　　题：Mg-Zn-Ca system ternary compound structure composition phase equilibrium 

摘      要：The phase equilibria and compositions in Mg-rich side at 300 ℃ were investigated in Mg-Zn-Ca ternary system through the equilibrated alloy method by using scanning electron microscopy,electron probe microanalysis,X-ray diffraction and transmission electron *** results show that two ternary compounds T1 and T2 can be in equilibrium with the Mg-based solid solution in Mg-Zn-Ca system.T1 phase is a linear compound with the composition region（molar fraction） of 15% Ca,20.5%-48.9% Zn and balanced Mg at 300 ℃.Its hexagonal structure parameters decrease with increasing Zn content,i.e.a=0.992-0.945 nm,c=1.034-1.003 nm.T2 phase has hexagonal structure with the composition region of 26.4%-28.4% Mg,63.2%-65.5% Zn and 7.1%-8.4% *** 300 ℃,the solubility of Zn in the Mg-based solid solution increases for the addition of Ca,the maximum solubility of Zn is 3.7%.Three-phase fields consisting of--Mg＋Mg2Ca＋T1,--Mg＋T1＋T2,--Mg＋T2＋MgZn and MgZn＋T2＋Mg2Zn3 exist in the Mg-Zn-Ca system at 300 ℃.