High molecular weight (C_(35)^+) n-alkanes of Neogene heavily biodegraded oil in the Qianmiqiao region,North China
High molecular weight (C_(35)^+) n-alkanes of Neogene heavily biodegraded oil in the Qianmiqiao region,North China作者机构：Key Laboratory of Petroleum Entrapment Mechanism of the Ministry of Education University of Petroleum Beijing China Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Geological Research Institute Dagang Oilfield (Group) Co. Ltd. Tianjin China
出 版 物：《Chinese Science Bulletin》 (CHINESE SCIENCE BULLETIN)
年 卷 期：2002年第47卷第16期
页 面：1402-1407页
核心收录：
学科分类：081803[工学-地质工程] 08[工学] 0818[工学-地质资源与地质工程]
基 金：This work was supported by the National Natural Science Foundation of China (Grant No. 40172056) the Research Found for the Doctoral Program of High Education (RFDP No. 2000042506) the Geological Research Institute, Dagang Oilfield (Group) Co. Ltd
主 题：biodegradation heavy oil high-temperature gas chro-matography (HTGC) high molecular weight (HMW) wax fraction HMW n-alkane.
摘 要：With wax content of 1.62%, heavy oil has been produced from the sandstone reservoirs of Neogene Guantao Formation (Ng1m). In the GC and GC-MS RIC profiles of its aliphatic fraction, n-alkanes are totally lost, which shows the result of heavy biodegradedation. However, the remaining trace C13-C36 n-alkanes can be still seen from its mlz 85 mass chromatogram. In addition, a complete series of C35-C73 high molecular weight (HMW) n-alkanes was detected by high-temperature gas chromatography (HTGC). The HMW R-alkane series shows a normal distribution pattern, a major peak at nC43, obvious odd-carbon-number predominance, CPI37-55 and OEP45-49 values up to 1.17 and 1.16-1.20 respectively. The present study not only has conformed the strong resistibility of HMW n-alkanes to biodegradation in crude oils as concluded by previous researchers, but also has provided some significant information on source input and maturity for the heavily biodegraded oil in the Qianmiqiao region.
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