Synthesis, Structure, and Photoluminescence Property of a Novel One-dimensional Inorganic-organic Hybrid Gallophosphate JGP-2

作     者：YANG Yu-lin FAN Rui-qing JIANG Zhao-hua WANG Fu-ping LIU Yun-ling PANG Wen-qin 

作者机构：Department of Chemistry Harbin Institute of Technology Harbin 150001 P. R. China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changehun 130012 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2009年第25卷第2期

页      面：127-131页

核心收录：

学科分类：081702[工学-化学工艺] 07[理学] 0809[工学-电子科学与技术（可授工学、理学学位）] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Supported by the National Natural Science Foundation of China(Nos.20671025 and 20771030) China Postdoctoral Science Foundation Funded Project(No.65204) Heilongjiang Province Natural Science Foundation, China(No.B200603) 

主　　题：Inorganic-organic hybrid Gallophosphate Hydrothermal synthesis Crystal Photoluminescence 

摘      要：A novel one-dimensional inorganic-organic hybrid gallophosphate compound, Ga（2,2＇-bipy）（HPO4）. （H2PO4）（denoted JGP-2） was synthesized hydrothermally with 2,2＇-bipyridine as a ligand and characterized by X-ray powder diffraction （XRD）, elemental analysis, inductively coupled plasma（ICP）, TGA analysis, solid-state ^31p NMR, and luminescence spectra and structurally determined by single-crystal X-ray diffraction analysis. JGP-2 crystallized in the triclinic system, space group P^-1（No.2）, with a=0.7818（1） nm, b=0.8611 （2） nm, c=1.0908（2） nm, V=0.6727（2） nm^3 and Z=2 with R1=0.0223. The structure of JGP-2 was built up by alternate arrangement of GaO4N2 octahedra, and HPO4（or H2PO4） tetrahedra to form an infinite one-dimensional corner-sharing-corner（CSC） chain. Through P sites, the CSC chains link with an unusual edge-sharing dimmer, Ga2F4（H2O）2, giving rise to a 4,10-membered ring net layered structure of JGP-7. On excitation at 254 nm, JGP-2 can emit strong blue light at ,λmax=388 rim. JGP-7 presents a strong fluorescence emission band centered at 394 nm（λex=340 nm）, the emission energy of JGP-7 is red-shifted comoared with that of JGP-2.