High temperature oxidation of inoculated high Si/SiMo ductile cast irons in air and combustion atmospheres
作者机构：National University of Science and Technology POLITEHNICA BucharestMaterials Science and Engineering Faculty313 Splaiul IndependenteiSector 6060042 BucharestRomania
出 版 物：《China Foundry》 (中国铸造（英文版）)
年 卷 期：2024年第21卷第5期
页 面：555-562页
核心收录：
学科分类：0817[工学-化学工程与技术] 08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学]
主 题：ductile iron spheroidal graphite Si/SiMo oxidation air/combustion atmospheres FeSiCaMgRE treatment Ca,Ca-Ba,Ca-RE inoculation structure characteristics
摘 要：The present work aims to investigate the effect of heating temperature(400,600 and 800°C)and inoculating elements(Ca,Ca-Ba,Ca-RE)on oxidation behavior of ductile irons containing 5.25%Si and 4.8%Si-2.3%Mo in dry air and combustion gas containing water vapour(natural gas burning).The oxidation is influenced by the gas atmosphere type,the iron alloying system,and the inoculating elements depending on the heating *** weight gain increases from 0.001%-0.1%(400°C)to 0.05%-0.70%(600°C)and up to 0.10%-2.15%(800°C).No particular effects of the considered influencing factors are found when heating at 400°C,while at 600°C,mainly the oxidation gas atmosphere type shows a visible *** the highest heating temperature of 800°C,a limited increase of the weight gain is found for dry air atmosphere(up to 0.25%),but it drastically increases for combustion atmospheres(0.65%-2.15%).The water vapour presence in the combustion atmosphere is an important oxidising factor at 600-800°*** alloying system appears to influence the oxidation behavior mainly at a heating temperature of 800°C in the combustion atmosphere,as evidenced by the lower weight gain in 5.25%silicon cast *** effects of inoculating elements increase with the heating temperature,with Ca and Ba-FeSi inoculation generally showing better *** inoculated with CaRE-FeSi exhibit a higher degree of *** results are in good relationship with the previous reported data:Ca-Ba-inoculation system appears to be better than simple Ca for improving the graphite parameters,while RE-bearing inoculant negatively affects the compactness degree of graphite particles in high-Si ductile *** the lower compactness degree is typical for graphite nodules in high-Si ductile irons,which negatively affects the oxidation resistance,it is necessary to employ specific metallurgical treatments to improve nodule ***,in particular,is a potential method to achieve this improvement.
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