A New Model for Predicting Ternary Thermodynamic Properties of Solution Phase and Its Application

作     者：Zhiyu QIAO Xianran XING Shuzhen DUAN University of Science and Technology Beijing,Beijing,100083,ChinaChaogui ZHENG Beijing University,Beijing,100871,China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：1993年第9卷第3期

页      面：199-204页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

主　　题：thermodynamic properties ternary system geometric asymmetric model 

摘      要：A new geometric asymmetric model for predicting the thermodynamic properties of ternary system from three sub-binaries is presented in this *** analytical expression with good calculating ac- curacy is most simple in all asymmetric *** new model was applied to predict the enthalpies of mixing of the ***-Ag-Sn and NaCl-KCl-CaCl_2 ternary systems which were in good agreements with experimental *** on thermodynamic principles,the importance of the choice of asymmetric component is also *** error analysis indicates that in the case of judging the asymmetric component in ternary system according to the thermodynamic criterion the deviation is *** is of great significance to improve the calculating accuracy for predicting thermodynamic properties of ternary solution phase from the sub-binary ones.