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Transformation of Bio-oil into BTX by Bio-oil Catalytic Cracking

生物油催化裂解转化制取三苯

作     者:朱九方 汪继聪 李全新 

作者机构:中国科学技术大学化学物理系合肥230026 

出 版 物:《Chinese Journal of Chemical Physics》 (化学物理学报(英文))

年 卷 期:2013年第26卷第4期

页      面:477-483,J0002页

核心收录:

学科分类:07[理学] 

基  金:supported by the National Key Basic Program of China 国家自然科学基金 

主  题:Bio-oil BTX Catalytic cracking 

摘      要:Production of benzene, toluene and xylenes (BTX) from bio-oil can provide basic feedstocks for the petrochemical industry. Catalytic conversion of bio-oil into BTX was performed by using different pore characteristics zeolites (HZSM-5, HY-zeolite, and MCM-41). Based on the yield and selectivity of BTX, the production of aromatics decreases in the following order: HZSM-5〉MCM-41〉HY-zeolite. The highest BTX yield from bio-oil using HZSM-5 reached 33.1% with aromatics selectivity of 86.4%. The reaction conditions and catalyst characterization were investigated in detail to make clear the optimal operating parameters and the relation between the catalyst structure and the production of BTX.

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