Transformation of Bio-oil into BTX by Bio-oil Catalytic Cracking
生物油催化裂解转化制取三苯作者机构:中国科学技术大学化学物理系合肥230026
出 版 物:《Chinese Journal of Chemical Physics》 (化学物理学报(英文))
年 卷 期:2013年第26卷第4期
页 面:477-483,J0002页
核心收录:
学科分类:07[理学]
基 金:supported by the National Key Basic Program of China 国家自然科学基金
主 题:Bio-oil BTX Catalytic cracking
摘 要:Production of benzene, toluene and xylenes (BTX) from bio-oil can provide basic feedstocks for the petrochemical industry. Catalytic conversion of bio-oil into BTX was performed by using different pore characteristics zeolites (HZSM-5, HY-zeolite, and MCM-41). Based on the yield and selectivity of BTX, the production of aromatics decreases in the following order: HZSM-5〉MCM-41〉HY-zeolite. The highest BTX yield from bio-oil using HZSM-5 reached 33.1% with aromatics selectivity of 86.4%. The reaction conditions and catalyst characterization were investigated in detail to make clear the optimal operating parameters and the relation between the catalyst structure and the production of BTX.