Multiscale and multicomponent layer by layer assembly of optical thin films triggered by electrochemical coupling reactions of N-alkylcarbazoles

作     者：Jian Zhang Shu-Sen Kang Zhe Zhang Mao Lia 

作者机构：State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China University of Chinese Academy of Sciences Beijing 100049 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2016年第27卷第4期

页      面：487-491页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：supported by the National Natural Science Foundation of China (Nos. 21374115, 51573181, and 21504088) the Hundred Talents Program, CAS, China 

主　　题：Layer-by-layer assembly Carbazole Electropolymerization Optical films Devices 

摘      要：The integration of multiscale and multicomponent of molecules and nanoparticles into thin films for applications requires the abilities of controlled their processing and assembly,which has been an great challenge because of the difficulty in manipulating the various materials such as small molecules,complexes,polymers,and inorganic nanomaterials through synergetic combinations of chemical or physical *** is of great significance to fabricate polymeric film materials straight on the conductive substrates with tunable morphologies and ***,unlimited electrochemical reactions（polymerization）have been usually leading to disadvantageous in ill-defined structure and highly doped *** to finding of exceptional electrochemical reaction（oligomerization）of N-alkylcarbazole,electrochemical layer by layer assembly has emerged as a promising strategy for a wide library of *** capability of this strategy can manipulate various molecules and nanoparticles into the scale and component controllable thin *** other electropolymerizable precursors such as aniline and thiophene,the resulting di-N-alkylcarbazole is transparent in the visible light region and thus does not impair the intrinsic properties of the components in the *** account highlights of the typical findings in investigating both single-and multi-components thin films as a forum for discussing new opportunities in exploiting novel designs and applications of optical thin films.