Thermal pyrolysis conversion of methane to hydrogen(H_(2)):A review on process parameters,reaction kinetics and techno-economic analysis

作     者：Yi Herng Chan Zhe Phak Chan Serene Sow Mun Lock Chung Loong Yiin Shin Ying Foong Mee Kee Wong Muhammad Anwar Ishak Ven Chian Quek Shengbo Ge Su Shiung Lam Yi Herng Chan;Zhe Phak Chan;Serene Sow Mun Lock;Chung Loong Yiin;Shin Ying Foong;Mee Kee Wong;Muhammad Anwar Ishak;Ven Chian Quek;Shengbo Ge;Su Shiung Lam

作者机构：PETRONAS Research Sdn.Bhd.(PRSB)Kawasan Institusi BangiLot 3288&3289Off Jalan Ayer ItamKajang 43000Malaysia PETRONAS Carbon Capture&Storage(CCS)EnterprisePETRONAS Twin TowersKuala Lumpur City CentreKuala Lumpur 50088Malaysia CO_(2)Research Center(CO2RES)Department of Chemical EngineeringUniversiti Teknologi PETRONASSeri Iskandar 32610Malaysia Department of Chemical Engineering and Energy SustainabilityFaculty of EngineeringUniversiti Malaysia Sarawak(UNIMAS)Kota Samarahan 94300Malaysia Institute of Sustainable and Renewable Energy(ISuRE)Universiti Malaysia Sarawak(UNIMAS)Kota Samarahan 94300Malaysia Higher Institution Centre of Excellence(HICoE)Institute of Tropical Aquaculture and Fisheries(AKUATROP)Universiti Malaysia TerengganuKuala Nerus 21030Malaysia Co-Innovation Center of Efficient Processing and Utilization of Forest ResourcesCollege of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China Center for Global Health Research(CGHR)Saveetha Medical CollegeSaveetha Institute of Medical and Technical Sciences(SIMATS)Saveetha UniversityChennai 602105India 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第8期

页      面：62-73页

核心收录：

学科分类：0202[经济学-应用经济学] 02[经济学] 081702[工学-化学工艺] 020205[经济学-产业经济学] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：support by the Education University of Hong Kong to perform this project under International Grant(UMT/International Grant/2020/53376) 

主　　题：Pyrolysis Methane Hydrogen Reaction kinetics Techno-economic analysis 

摘      要：Hydrogen(H_(2))is a promising renewable energy which finds wide applications as the world gears toward low-carbon ***,current H_(2) production via steam methane reforming of natural gas or gasification of coal are laden with high CO_(2) ***,methane(CH_(4))pyrolysis has emerged as a potential technology to generate low-carbon H_(2) and solid *** this review,the current state-of-art and recent progress of H_(2) production from CH_(4) pyrolysis are reviewed in *** such as funda-mental mechanism and chemistry involved,effect of process parameters on the conversion efficiency and reaction kinetics for various reaction media and catalysts are elucidated and critically ***-ature,among other factors,plays the most critical influence on the methane pyrolysis *** metal/salt could lower the operating temperature of methane pyrolysis to1000℃.Based on the reaction kinetics,metal-based cata-lysts were more efficient in lowering the activation energy of the reaction to 29.5-88 kJ/mol from that of uncatalyzed reaction(147-420.7 kJ/mol).Besides,the current techno-economic performance of the pro-cess reveals that the levelized cost of H_(2) is directly influenced by the sales price of carbon(by-product)generated,which could offset the overall ***,the main challenges of reactor design for efficient product separation and retrieval,as well as catalyst deactivation/poisoning need to be debottlenecked.