A thermodynamic perspective on electrode poisoning in solid oxide fuel cells

作     者：Kevin Huang Kevin Huang

作者机构：Department of Mechanical EngineeringUniversity of South CarolinaColumbiaUSA 

出 版 物：《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报（英文版）)

年 卷 期：2024年第31卷第6期

页      面：1449-1455页

核心收录：

学科分类：0808[工学-电气工程] 081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the U.S.Department of Energy’s Office of Energy Efficiency and Renewable Energy(EERE)under the Fuel Cell Technologies Office(FCTO)(No.DE-EE-0008842) the Office of Fossil Energy and Carbon Management under National Energy Technology Lab(No.DE-FE-0032111) 

主　　题：impurities air fuel reaction activity 

摘      要：A critical challenge to the commercialization of clean and high-efficiency solid oxide fuel cell(SOFC)technology is the insuf-ficient stack lifespan caused by a variety of degradation mechanisms,which are associated with cell components and chemical *** components related degradation refers to thermal/chemical/electrochemical deterioration of cell materials under operating conditions,whereas the latter regards impurities in feedstocks of oxidant(air)and reductant(fuel).This article provides a thermodynamic perspective on the understanding of the impurities-induced degradation mechanisms in *** discussion focuses on using thermodynamic ana-lysis to elucidate poisoning mechanisms in cathodes by impurity species such as Cr,CO_(2),H_(2)O,and SO_(2) and in the anode by species such as S(or H_(2)S),SiO_(2),and P_(2)(or PH_(3)).The author hopes the presented fundamental insights can provide a theoretical foundation for search-ing for better technical solutions to address the critical degradation challenges.