Embedding laser-generated CdTe nanocrystals into ultrathin ZnIn_(2)S_(4) nanosheets with sulfur vacancies for boosted photocatalytic H_(2) evolution

作     者：Z.G.Tai G.T.Sun X.H.Zhang X.B.Yang T.Wang Z.Y.Fang Q.Ye L.C.Jia H.Q.Wang Z.G.Tai;G.T.Sun;X.H.Zhang;X.B.Yang;T.Wang;Z.Y.Fang;Q.Ye;L.C.Jia;H.Q.Wang

作者机构：State Key Laboratory of Solidification ProcessingCenter for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Research&Development Institute of Northwestern Polytechnical University in ShenzhenShenzhen 518063China School of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2023年第166卷第35期

页      面：113-122页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070205[理学-凝聚态物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0702[理学-物理学] 0812[工学-计算机科学与技术（可授工学、理学学位）] 

基　　金：The research was sponsored by the National Natural Science Foundation of China(Nos.52172101 and 51872240) the National Key R&D Program for International Cooperation(No.2021YFE0115100) Shaanxi Province Key Research and Develop-ment Program(No.2021ZDLGY14-08) the Fundamental Research Funds for the Central Universities(No.3102019JC005) the Guangdong Basic and Applied Basic Research Foundation(No.2022A1515110228).The authors thank the Analysis and Test Center of Northwestern Polytechnical University and Shaanxi Materials Analysis and Research Center for XPS,SEM,and TEM characterizations 

主　　题：Photocatalysis Hydrogen evolution Laser irradiation Heterostructure Sulfur vacancies 

摘      要：To suppress the inner charge recombination and inject vast electrons,CdTe nanocrystals are embedded into ultrathin ZnIn_(2)S_(4) nanosheets to construct ZnIn_(2)S_(4)/CdTe heterostructures,where the nanocrystals are generated by a laser irradiation *** optimal ZnIn_(2)S_(4)/CdTe heterojunction exhibits an excellent catalytic activity of 24.3 mmol/h/g,which is relatively high among the ZnIn_(2)S_(4)-based photocatalysts with-out noble *** enhancement is ascribed to a win-win mechanism of nanoscale heterojunctions and sulfur *** strong electron coupling effect,which is verified by density functional the-ory(DFT)calculations,impels the photo-generated electrons transfer from CdTe to ZnIn_(2)S_(4),boosting the charge ***,the sulfur vacancies existing in ZnIn_(2)S_(4) can capture photoelectrons and act as active sites,facilitating the H_(2) generation *** addition,the ZnIn_(2)S_(4) base and the ZnIn_(2)S_(4)/CdTe heterojunction also possess an evident photothermal effect and renewable cycle phenomena,enhancing the photocatalytic *** research provides new insights into the regulation of charge transfer through embedding nanocrystals.