Access to Versatile Functionalized Cu(Ⅲ) Complexes Enabled by Direct Transmetalation to Well-Defined Copper(Ⅲ) Fluoride Complex Me_(4)N^(+)[Cu(CF_(3))_(3)F]^(-)

作     者：Guangyu Wang Huaiyuan Li Xuebing Leng Long Lu Qilong Shen Guangyu Wang;Huaiyuan Li;Xuebing Leng;Long Lu;Qilong Shen

作者机构：Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced MaterialsShanghai Institute of Organic ChemistryUniversity of Chinese Academy of SciencesChinese Academy of Sciences345 Lingling LuShanghai 200032China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2024年第42卷第10期

页      面：1107-1113页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the financial support from the National Key Research and Development Program of China(No.2021YFF0701700) the National Natural Science Foundation of China(22061160465) 

主　　题：Fluorine Copper Cu(Ⅲ) Cu(Ⅲ)fluoride Trifluoromethyl 

摘      要：The invention of a well-defined Cu(Ⅲ)fluoride complex Me_(4)N^(+)[Cu(CF_(3))_(3)(F)]^(-)1 enabled to access a versatile of functionalized Cu(Ⅲ)complexes[Me_(4)N]^(+)[Cu(X)(CF_(3))_(3)]^(-)(X=C_(6)F_(5),C_(6)F_(5)C≡C,CN,Cl,N_(3),^(t)BuOO,SCN,OAc,SAr),many of them for the first *** availability of these complexes allowed us to evaluate the trans-influence order of ligand in Cu(Ⅲ)complexes:BnCF_(3)^(-)C_(6)F_(5)^(-)N_(3)^(-)py~CH_(3)^(-)~C_(6)F_(5)C≡CNO_(2)PhO^(-)~^(t)BuOO^(-)~CH_(3)COO^(-)F^(-).