MOF-derived Cu embedded into N-doped mesoporous carbon as a robust support of PdAu nanocatalysts for ethanol electrooxidation

作     者：Yu-Fu Huang Peng Wu Jun-Ping Tang Jian Yang Jing Li Shuai Chen Xue-Ling Zhao ChengChen Bin-Wei Zhang Yan-Yun Ma Wei-Heng Shi Dong-Hai Lin Shi-Gang Sun Yu-Fu Huang;Peng Wu;Jun-Ping Tang;Jian Yang;Jing Li;Shuai Chen;Xue-Ling Zhao;Cheng Chen;Bin-Wei Zhang;Yan-Yun Ma;Wei-Heng Shi;Dong-Hai Lin;Shi-Gang Sun

作者机构：School of Energy and MaterialsShanghai Engineering Research Center of Advanced Thermal Functional MaterialsShanghai Key Laboratory of Engineering Materials Application and EvaluationShanghai Polytechnic UniversityShanghai201209China State Key Laboratory of Physical Chemistry of Solid SurfacesDepartment of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China School of Chemistry and Chemical EngineeringChongqing UniversityChongqing401331China Center of Advanced Energy Technology and ElectrochemistryInstitute of Advanced Interdisciplinary StudiesChongqing UniversityChongqing400044China Institute of Functional Nano&Soft Materials(FUNSOM)Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou215123China Department of Materials Science and EngineeringDrexel UniversityPhiladelphiaPA19104USA 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2024年第43卷第3期

页      面：1083-1094页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：financially supported by the Program for Professor of Special Appointment(Eastern Scholar)at SIHL Project of Shanghai Municipal Science and Technology Commission(No.22DZ2291100) Open Fund of Anhui International Joint Research Center for Nano Carbon-based Materials and Environmental Health(No.NCMEH2022Y02) Gaoyuan Discipline of Shanghai-Materials Science and Engineering,and Shanghai Polytechnic University-Drexel University Joint Research Center for Optoelectronics and Sensing supported by the Science Fund for Distinguished Young Scholars of Fujian Province(No.2019J06027) the Open Project of Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices(Soochow University)(No.KS2022) Collaborative Innovation Center of Suzhou Nano Science&Technology the 111 Project Joint International Research Laboratory of Carbon-Based Functional Materials and Devices 

主　　题：Metal-organic frameworks(MOFs) N-doped Mesoporous carbon PdAu Ethanol electrooxidation 

摘      要：Metal-organic frameworks(MOFs)h ave attracted widespread attention due to their large surface area and porous *** designing the nanostructures of MOFs to promote their application in ethanol electrooxidation is still a ***,a novel Cu-NCNs(Cu-nitrogen-doped carbon nanotubes)support was synthesized by pyrolysis of melamine(MEL)and Cu-ZIF-8 together,and then,Pd-Au nanoalloys were loaded by sodium borohydride reduction method to prepare PdAu@Cu-NCNs *** generating mesoporous carbon with high specific surface area and favorable electron and mass transport can be used as a potential excellent carrier for PdAu *** addition,the balance of catalyst composition and surface structure was tuned by controlling the content of Pd and ***,the best-performed Pd_(2)Au_(2)@Cu-NCN-1000-2(where 1000 means the carrier calcination temperature,and 2 means the calcination constant temperature time)catalyst exhibits better long-term stability and electrochemical activity for ethanol oxidation in alkaline media(4.80 A·mg^(-1)),which is 5.05 times higher than that of commercial Pd/C(0.95 A·mg^(-1)).Therefore,this work is beneficial to further promoting the application of MOFs in direct ethanol fuel cells(DEFCs)and can be used as inspiration for the design of more efficient catalyst support structures.