Encapsulation of metal layers within metal-organic frameworks as hybrid thin films for selective catalysis

作     者：Zhiling Xu Weina Zhang Jiena Weng Wei Huang Danbi Tian Fengwei Huo 

作者机构：Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University (Nanjing Tech) 30 South Puzhu Road Nanjing 211816 China College of Science Nanjing Tech University 30 South Puzhu Road Nanjing 211816 China 

出 版 物：《Nano Research》 (纳米研究（英文版）)

年 卷 期：2016年第9卷第1期

页      面：158-164页

核心收录：

学科分类：081705[工学-工业催化] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：The project was supported by the Jiangsu Provincial Founds for Distringuished Young Scholars (No. 55135011)  start-up fund at Nanjing Tech University and the National Natural Science Foundation (Nos. 21574065 and 21504043) 

主　　题：metal-organic frameworks catalysis hybrid thin films metal layers composition 

摘      要：A facile encapsulation strategy for the preparation of metal layer/metal-organic framework （metal/MOF） hybrid thin films, by alternately growing MOF thin films and sputter-coating metal layers, is reported. The controlled species of the MOF thin films and metal layers, as well as the designed thickness of MOF thin films, endow the resulting hybrid thin films with improved functional and design flexibility. Importantly, the metaL/MOF hybrid thin films, with well-defined sandwich structures, exhibit excellent selective catalytic activity, derived from MOFs acting as molecular sieves and the metal layers providing active sites.