Polymerization reaction in restricted space of layered double hydroxides(LDHs)

作     者：SILichun CAIFuli WANGZhiqing DUANXue 

作者机构：KeyLaboratoryofScienceandTechnologyofControllableChemicalReactionsBox98MinistryofEducationBeijingUniversityofChemicalTechnologyBeijing100029China DepanmentofchemistryTsinghuaUniversityBeijing100084China 

出 版 物：《Chinese Science Bulletin》 (CHINESE SCIENCE BULLETIN)

年 卷 期：2004年第49卷第23期

页      面：2459-2463页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：H020821260120 Smoking Research Foundation,SRF 

主　　题：聚合反应 羟化物 LDHs 共沉淀方法 钠 苯乙烯 磺酸盐 

摘      要：This paper reported the preparation of styrene sulfonate intercalated layered double hydroxides (LDHs) material, SS-LDHs by coprecipitation method, followed by in-situ polymerisation of the monomers in the interlayer space of LDHs. The polymerisation reaction was monitored by UV and NMR. It is confirmed that when the reaction oc- curred at 100℃ for 24 h, part of monomers did not react. When the reaction was carried out at 150℃, the polymeriza- tion of the intercalated monomers is complete to afford the polymer intercalated product PSS-LDHs. During the polym- erization process, the layered structure remains well. At the same time the gallery height increases with the lengthening of reaction time. This is preliminarily because that the PSS becomes more swelling with the amount of water it absorbs due to its hygroscopicity property.