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Recent advances and challenges of nitrogen/nitrate electro catalytic reduction to ammonia synthesis

作     者:Junwen CAO Yikun HU Yun ZHENG Wenqiang ZHANG Bo YU Junwen CAO;Yikun HU;Yun ZHENG;Wenqiang ZHANG;Bo YU

作者机构:Institute of Nuclear and New Energy Technology(INET)Collaborative Innovation Center of Advanced Nuclear Energy TechnologyTsinghua UniversityBeijing 100084China Department of Chemical EngineeringUniversity of WaterlooWaterlooOntario N2L 3G1Canada Institute of New Energy Materials and EngineeringSchool of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China 

出 版 物:《Frontiers in Energy》 (能源前沿(英文版))

年 卷 期:2024年第18卷第2期

页      面:128-140页

核心收录:

学科分类:0820[工学-石油与天然气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

主  题:electrochemical ammonia synthesis nitrogen nitrate nitrogen reduction reaction(NRR)to ammonia nitrate reduction reaction(NO_(3)^(-))RR 

摘      要:The Haber-Bosch process is the most widely used synthetic ammonia technology at *** its invention,it has provided an important guarantee for global food ***,the traditional Haber-Bosch ammonia synthesis process consumes a lot of energy and causes serious environmental *** the serious pressure of energy and environment,a green,clean,and sustainable ammonia synthesis route is urgently *** synthesis of ammonia is a green and mild new method for preparing ammonia,which can directly convert nitrogen or nitrate into ammonia using electricity driven by solar,wind,or water energy,without greenhouse gas and toxic gas ***,the basic mechanism of the nitrogen reduction reaction(NRR)to ammonia and nitrate reduction reaction(NO_(3)^(-))to ammonia were *** representative approaches and major technologies,such as lithium mediated electrolysis and solid oxide electrolysis cell(SOEC)electrolysis for NRR,high activity catalyst and advanced electrochemical device fabrication for(NO_(3)^(-))RR and electrochemical ammonia synthesis were *** on the above discussion and analysis,the main challenges and development directions for electrochemical ammonia synthesis were further proposed.

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