Catalytic effect in lithium metal batteries: From heterogeneous catalyst to homogenous catalyst

作     者：Haining Fan Xuan-Wen Gao Hailong Xu Yichun Ding Shi-Xue Dou Wen-Bin Luo Haining Fan;Xuan-Wen Gao;Hailong Xu;Yichun Ding;Shi-Xue Dou;Wen-Bin Luo

作者机构：School of Fashion and TextilesThe Hong Kong Polytechnic UniversityHong Kong 100872China Institute for Energy Electrochemistry and Urban Mines MetallurgySchool of MetallurgyNortheastern UniversityShenyang 110819LiaoningChina Institute of Energy Materials ScienceUniversity of Shanghai for Science and TechnologyShanghai 200000China State Key Laboratory of Solidification ProcessingSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi'an 710000ShaanxiChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2024年第90卷第3期

页      面：305-326,I0008页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0813[工学-建筑学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(52272194) Liaoning Revitalization Talents Program(XLYC2007155) 

主　　题：Energy storage and conversion Metal battery Sulfur battery Air battery Catalytic effect Heterogeneous catalyst Homogeneous catalyst 

摘      要：Lithium metal batteries are regarded as prominent contenders to address the pressing needs owing to the high theoretical *** the broader implementation,the primary obstacle lies in the intricate multi-electron,multi-step redox reaction associated with sluggish conversion kinetics,subsequently giving rise to a cascade of parasitic *** order to smooth reaction kinetics,catalysts are widely introduced to accelerate reaction rate via modulating the energy *** past decades,a large amount of research has been devoted to the catalyst design and catalytic mechanism exploration,and thus the great progress in electrochemical performance has been ***,it is necessary to make a comprehensive review toward key progress in catalyst design and future development *** this review,the basic mechanism of lithium metal batteries is provided along with corresponding advantages and existing challenges detailly *** main catalysts employed to accelerate cathode reaction with emphasis on their catalytic mechanism are summarized as ***,the rational design and innovative direction toward efficient catalysts are suggested for future application in metal-sulfur/gas battery and *** review is expected to drive and benefit future research on rational catalyst design with multi-parameter synergistic impacts on the activity and stability of next-generation metal battery,thus opening new avenue for sustainable solution to climate change,energy and environmental issues,and the potential industrial economy.