Improvements in mechanical, corrosion, and biocompatibility properties of Mg–Zr–Sr–Dy alloys via extrusion for biodegradable implant applications
作者机构:School of EngineeringRMIT UniversityMelbourneVictoria 3001Australia School and Hospital of StomatologyWenzhou Medical UniversityWenzhou 325027China
出 版 物:《Journal of Magnesium and Alloys》 (镁合金学报(英文))
年 卷 期:2023年第11卷第10期
页 面:3840-3865页
核心收录:
学科分类:0831[工学-生物医学工程(可授工学、理学、医学学位)] 08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0836[工学-生物工程]
基 金:the financial support for this research by the Australian Research Council (ARC) through the Future Fellowship (FT160100252) the Discovery Project (DP170102557)
主 题:Corrosion Microstructure mechanical properties Cytotoxicity Mg–Zr–Sr–Dy alloy
摘 要:In this study,extrusion was performed on Mg-Zr-Sr-Dy alloys for improving their mechanical,corrosion,and biocompatibility *** of extrusion and alloying elements on the microstructural characteristics,tensile and compressive strengths,corrosion behavior,and biocompatibility were *** Mg-Zr-Sr-Dy alloys were composed of an α-Mg matrix containing {10■2} extension twins and secondary phases of intermetallic compounds Mg_(17)Sr_(2) and Mg_(2)*** of basal and rare earth(RE) textures was observed in the extruded alloys and an increase in Dy content to 2 wt.% resulted in texture randomization and strengthening of the RE component,mainly due to particle-stimulated nucleation and a change from discontinuous dynamic recrystallization to continuous dynamic recrystallization,which also led to an improved tension-compression yield asymmetry of *** of the alloys significantly enhanced their tensile and compressive properties due to improved distribution of alloying elements and formation of *** rates tested by hydrogen evolution testing,potentiodynamic polarization,and electrical impedance spectroscopy showed similar trends for each composition,and the lowest corrosion rate of 3.37 mmy^(-1) was observed for the Mg-1Zr-0.5Sr-1Dy in the potentiodynamic polarization ***_(2)O_(3) was observed in the inner layers of the Mg(OH)_(2) protective films,whose protective efficacy was confirmed by charge-transfer and film resistances.A comparison among the minimum CRs observed in this study and previously studied as-cast Mg-Zr-Sr-Dy and extruded Mg-Zr-Sr alloys,demonstrates that both the extrusion process and addition of Dy in Mg-Zr-Sr improved the ***,extruded Mg-Zr-Sr-Dy alloys showed improved cell viability and adhesion of human osteoblast-like SaOS2 cells due to increased corrosion resistance and enhanced Sr distribution within the Mg matrix.