Emerging two-dimensional Mo-based materials for rechargeable metal-ion batteries:Advances and perspectives

作     者：Qingqing Ruan Yuehua Qian Mengda Xue Lingyun Chen Qichun Zhang Qingqing Ruan;Yuehua Qian;Mengda Xue;Lingyun Chen;Qichun Zhang

作者机构：Department of Applied ChemistrySchool of Chemistry and Chemical EngineeringChongqing UniversityChongqing 401331China Department of Materials Science and EngineeringCity University of Hong Kong999077Hong KongChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2024年第89卷第2期

页      面：487-518,I0012页

核心收录：

学科分类：0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(No.21676036) the Natural Science Foundation of Chongqing(No.CSTB2023NSCQ-MSX0580) the Graduate Research and Innovation Foundation of Chongqing(No.CYB22043 and CYS22073) 

主　　题：Molybdenum-based materials Two-dimensional materials Lithium-ion batteries Sodium-ion batteries Zinc-ion batteries 

摘      要：With the rapid development of rechargeable metal-ion batteries(MIBs)with safety,stability and high energy density,significant efforts have been devoted to exploring high-performance electrode *** recent years,two-dimensional(2D)molybdenum-based(Mo-based)materials have drawn considerable attention due to their exceptional characteristics,including low cost,unique crystal structure,high theoretical capacity and controllable chemical ***,like other transition metal compounds,Mo-based materials are facing thorny challenges to overcome,such as slow electron/ion transfer kinetics and substantial volume changes during the charge and discharge *** this review,we summarize the recent progress in developing emerging 2D Mo-based electrode materials for MIBs,encompassing oxides,sulfides,selenides,*** introducing the crystal structure and common synthesis methods,this review sheds light on the charge storage mechanism of several 2D Mo-based materials by various advanced characterization *** latest achievements in utilizing 2D Mo-based materials as electrode materials for various MIBs(including lithium-ion batteries(LIBs),sodium-ion batteries(SIBs)and zinc-ion batteries(ZIBs))are discussed in ***,the modulation strategies for enhancing the electrochemical performance of 2D Mo-based materials are highlighted,focusing on heteroatom doping,vacancies creation,composite coupling engineering and nanostructure ***,we present the existing challenges and future research directions for 2D Mo-based materials to realize high-performance energy storage systems.