Oxide-supported metal catalysts for anaerobic NAD+regeneration with concurrent hydrogen production

作     者：Jianwei Li Joseph W.H.Burnett Claudia Martinez Macias Russell F.Howe Xiaodong Wang Jianwei Li;Joseph W.H.Burnett;Claudia Martinez Macias;Russell F.Howe;Xiaodong Wang

作者机构：Chemical EngineeringSchool of EngineeringLancaster UniversityLancaster LA1 4YWUnited Kingdom Chemistry DepartmentUniversity of AberdeenAberdeen AB24 3UEUnited Kingdom 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第2期

页      面：263-267页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：supported by the EPSRC New Horizons grants(Nos.EP/V048635/1 and EP/X018172/1) We are also grateful for support from the UK Catalysis Hub funded by EPSRC grant reference EP/R026645/1 

主　　题：NAD+regeneration Heterogeneous catalyst Hydrogenase mimic Hydrogen binding energy Hydrogen production 

摘      要：We report SiO_(2)-supported monometallic Pt,Pd,Au,Ni,Cu and Co catalysts for proton-driven NAD+regeneration,co-producing H_(2).All metals are fully selective to NAD+where the order of turnover frequencies(PtPdCuAu,Ni and Co)coincides with those otherwise observed in electrochemical hydrogen evolution *** has revealed that NADH is capable of converting the metal sites into a“cathodewithout an external potential and the NADH to NAD+reaction involves transferring electron and hydrogen atom ***-deficient Ptδ+(on CeO_(2))enhances TOF and the heterogeneous Pt/CeO_(2) catalyst is recyclable without losing any activity/selectivity.