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Preparation of SiC coated graphite composite powders by nitriding combustion synthesis

作     者:Biao Zhang Wenqi Xie Huaizhi Lin Zhilei Wei Zhichao Xiao Kai He Zhongqi Shi Biao Zhang;Wenqi Xie;Huaizhi Lin;Zhilei Wei;Zhichao Xiao;Kai He;Zhongqi Shi

作者机构:State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’an 710049China China Nuclear Power Engineering Co.Ltd.Beijing 100840China 

出 版 物:《Journal of Advanced Ceramics》 (先进陶瓷(英文))

年 卷 期:2023年第12卷第10期

页      面:1930-1945页

核心收录:

学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 

基  金:supported by the National Natural Science Foundation of China(No.92163112) the Natural Science Foundation of Shaanxi Province(No.2023-JC-JQ-29) the Innovative Scientific Program of CNNC,and the Opening Foundation of Shaanxi Key Laboratory of Aerospace Composites 

主  题:SiC-coated graphite powders nitriding combustion synthesis(CS) antioxidation properties 

摘      要:Ceramic-coated graphite powders are considered as effective raw materials to fabricate three-dimensional continuous ceramic skeleton-reinforced graphite matrix composites which can overcome their inherent poor densification and improve their mechanical and antioxidation ***,the morphology and thickness regulation of ceramic coatings on graphite particles are still a great ***,SiC-coated graphite(graphite@SiC)powders were prepared by nitriding combustion synthesis using Si and graphited mesocarbon microbead(MCMB)as raw powders with polytetrafluoroethylene(PTFE)as a *** effects of the PTFE content and the Si/MCMB molar ratio on the phase composition and coating morphology were *** phase transition and microstructure evolution of a combustion synthesis(CS)process were revealed by a gas-released quenching *** the Si/MCMB molar ratio was 1:3 and the PTFE content was 10 wt%,the thickness of the SiC coating synthesized under 2 MPa N_(2)reached 1.14μ*** corresponding sintered graphite@SiC composite had relative density of 99.2%and flexural strength of 231 MPa,accompanied by a significant improvement in high-temperature antioxidation *** as-synthesized graphite@SiC powders with good sinterability and antioxidation properties show great promise for applications in the nuclear industry and other extreme fields.

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