Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia

作     者：Daming Feng Lixue Zhou Timothy J.White Anthony K.Cheetham Tianyi Ma Fengxia Wei Daming Feng;Lixue Zhou;Timothy J.White;Anthony K.Cheetham;Tianyi Ma;Fengxia Wei

作者机构：College of ChemistryLiaoning UniversityShenyang 110036People’s Republic of China School of Materials Science and EngineeringNanyang Technological University50 Nanyang AvenueSingapore 639798Singapore Materials Research LaboratoryUniversity of CaliforniaSanta BarbaraCA 93106USA School of ScienceRMIT UniversityMelbourneVIC 3000Australia Institute of Materials Research and Engineering(IMRE)Agency for ScienceTechnology and Research(A^(*)STAR)2 Fusionopolis WayInnovis 08‑03Singapore 138634Singapore 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2023年第15卷第11期

页      面：205-240页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：support from the Natural Science Foundation of Liaoning Province(general program)(2020-MS-137) T.J.White would like to thank the MOE2019-T2-2-032 grant and Monetary Academic Resources for Research Grant 001561-00001 in Nanyang Technological University,Singapore T.Ma would like to thank the National Natural Science Foundation of China(Nos.52071171,52202248) Liaoning BaiQianWan Talents Program(LNBQW2018B0048) Shenyang Science and Technology Project(21-108-9-04) Australian Research Council(ARC)through Future Fellowship(FT210100298,FT210100806) Discovery Project(DP220100603) Linkage Project(LP210100467,LP210200504,LP210200345,LP220100088) Industrial Transformation Training Centre(IC180100005)schemes the Australian Government through the Cooperative Research Centres Projects(CRCPXIII000077) F.Wei would like to thank the A^(*)STAR career development fund C210112054 Singapore structural metal alloy program grant No.A18b1B0061.A.K.Cheetham would like to thank the Ras al Khaimah Centre for Advanced Materials 

主　　题：Metal–organic frameworks Electrosynthesis of ammonia Nitrogen reduction reactions Nitrate reduction reactions 

摘      要：Electrocatalytic synthesis under mild conditions has become increasingly important as one of the practical alternatives for industrial applications,especially for the green ammonia(NH_(3))industry.A properly engineered electrocatalyst plays a vital role in the realization of superior catalytic *** various types of promising nanomaterials,metal–organic frameworks(MOFs)are competitive candidates for developing efficient electrocatalytic NH_(3) synthesis from simple nitrogen-containing molecules or ions,such as N_(2) and NO_(3)^(−).In this review,recent advances in the development of electrocatalysts derived from MOFs for the electrosynthesis of NH_(3) are collected,categorized,and discussed,including their application in the N_(2) reduction reaction(NRR)and the NO_(3)^(−)reduction reaction(NO3RR).Firstly,the fundamental principles are illustrated,such as plausible mechanisms of NH_(3) generation from N_(2) and NO_(3)^(−),the apparatus of corresponding electrocatalysis,parameters for evaluation of reaction efficiency,and detection methods of yielding NH_(3).Then,the electrocatalysts for NRR processes are discussed in detail,including pristine MOFs,MOF-hybrids,MOF-derived N-doped porous carbons,single atomic catalysts from pyrolysis of MOFs,and other MOF-related ***,MOF-related NO3RR processes are also listed and ***,the existing challenges and prospects for the rational design and fabrication of electrocatalysts from MOFs for electrochemical NH_(3) synthesis are presented,such as the evolution of investigation methods with artificial intelligence,innovation in synthetic methods of MOF-related catalysts,advancement of characterization techniques,and extended electrocatalytic reactions.