Engineering in amino acid-functionalized double-layer heteropolymolybdates:from structural control to catalytic activity

作     者：Lu-Lu Liu Yan-Hu Wang Xin-Yu Xiao Ke-Wei Tong Yue Zhao Chao-Qin Chen Jing Du Peng Yang Lu-Lu Liu;Yan-Hu Wang;Xin-Yu Xiao;Ke-Wei Tong;Yue Zhao;Chao-Qin Chen;Jing Du;Peng Yang

作者机构：College of Chemistry and Chemical EngineeringAdvanced Catalytic Engineering Research Center of the Ministry of EducationHunan UniversityChangsha410082China Testing and Analysis CenterHebei Normal UniversityShijiazhuang050024China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2023年第42卷第10期

页      面：3345-3353页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：financially supported by the National Natural Science Foundation of China (No. 22001066) the Natural Science Foundation of Hunan Province (Nos. 2021JJ40049 and 2022JJ20007) the Scientific Research Foundation of the Education Department of Hunan Province (No. 21B0028) the Science and Technology Innovation Program of Hunan Province (No. 2022RC1115) 

主　　题：structural layer double 

摘      要：A reexamination of the structural constraints on the amino acid-functionalized heteropolymolybdates has afforded four polyanions,namely the double-layer [(SeO_(3))_(2)Mo_(12)O_(36)(CH_(3)COO)_(3)]^(7-)(1),[(SeO_(3))_(1.3)(HPO_(3))_(0.7)Mo_(12)O_(36)(NH_(3)CH_(2)COO)_(3)]^(4-)(2),[(SeO_(3))_(1.4)(HPO_(3))_(0.6)Mo_(12)O_(36)(LNH_(3)C_(2)H_(3)OHCOO)_(3)]^(4-)(3),and the mono-layer [(SeO_(3))-Mo_6O_(18)(L-NH_(3)C_(2)H_(3)OHCOO)_(3)]^(2-)(4),which were crystallized as the hydrated ammonium salts.