The effect of pulse voltage rise rate on the polypropylene surface hydrophilic modification by ns pulsed nitrogen DBD

作     者：刘峰 李舒豪 赵昱雷 Shakeel AKRAM 张丽 方志 Feng LIU;Shuhao LI;Yulei ZHAO;Shakeel AKRAM;Li ZHANG;Zhi FANG

作者机构：College of Electrical Engineering and Control ScienceNanjing Tech UniversityNanjing 211816People's Republic of China 

出 版 物：《Plasma Science and Technology》 (等离子体科学和技术（英文版）)

年 卷 期：2023年第25卷第10期

页      面：6-14页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：supported by National Natural Science Foundation of China (Nos. 52037004, 51777091 and52250410350) Postgraduate Research&Practice Innovation Program of Jiangsu Province (No.KYCX22_1314) 

主　　题：dielectric barrier discharge pulse rise time material surface modification polypropylene uniformity 

摘      要：The nanosecond(ns) pulsed nitrogen dielectric barrier discharge(DBD) is employed to enhance the hydrophilicity of polypropylene(PP) surface and improve its application *** discharge characteristics of the ns pulsed nitrogen DBD with different pulse rise times(from 50to 500 ns) are investigated by electrical and optical diagnostic methods and the discharge uniformity is quantitatively analyzed by image processing *** characterize the surface hydrophilicity,the water contact angle(WCA) is measured,and the physical morphology and chemical composition of PP before and after modification are analyzed to explore the effect of plasma on PP *** is found that with increasing pulse rise time from 50 to 500 ns,DBD uniformity becomes worse,energy efficiency decreases from 20% to 10.8%,and electron density decrease from 6.6 × 10^(11)to 5.5 × 10^(11)cm^(-3).The tendency of electron temperature is characterized with the intensity ratio of N_(2)/N_(2)^(+)emission spectrum,which decreases from 17.4 to15.9 indicating the decreasing of T_(e) with increasing pulse rise time from 50 to 500 *** PP surface treated with 50 ns pulse rise time DBD has a lower WCA(~47°),while the WCA of PP treated with 100 to 500 ns pulse rise time DBD expands gradually(~50°–57°).According to the study of the fixed-point WCA values,the DBD-treated PP surface has superior uniformity under50 ns pulse rise time(3° variation) than under 300 ns pulse rise time(8° variation).After DBD treatment,the increased surface roughness from 2.0 to 9.8 nm and hydrophilic oxygencontaining groups on the surface,***(-OH) and carbonyl(C=O) have played the significant role to improve the sample’s surface *** short pulse voltage rise time enhances the reduced electric field strength(E/n) in the discharge space and improves the discharge uniformity,which makes relatively sufficient physical and chemical reactions have taken place on the PP surface,resulting in better treatment uniformit