Alkali Ionic Conductivity in Inorganic Glassy Electrolytes
Alkali Ionic Conductivity in Inorganic Glassy Electrolytes作者机构：Department of Environmental Science United Tribes Technical College Bismarck USA School of Arts and Science University of Mount Olive Mount Olive USA Intertribal Research and Resource Center United Tribes Technical College Bismarck USA
出 版 物：《Journal of Materials Science and Chemical Engineering》 (材料科学与化学工程（英文）)
年 卷 期：2023年第11卷第7期
页 面：31-72页
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
主 题：Glass Electrolyte Solid State Ionic Glass Battery Charge Antiperovskite Ionic Conductivity
摘 要：Glassy electrolytes could be a potential candidate for all-solid-state batteries that are considered new-generation energy storage devices. As glasses are one of the potential fast ion-conducting electrolytes, progressive advances in glassy electrolytes have been undergoing to get commercial attention. However, the challenges offered by ionic conductivity at room temperature (10−5 - 10−3 S∙cm−1) in comparison to those of organic liquid electrolytes (10−2 S∙cm−1) hindered the applicability of such electrolytes. To enhance the research development on ionic conductivity, the overall picture of the ionic conductivity of glassy electrolytes is reviewed in this article with a focus on alkali oxide and sulfide glasses. We portray here the techniques applied for alkali ion conductivity enhancement, such as methods of glass preparation, host optimization, doping, and salt addition for enhancing alkali ionic conductivity in the glasses.
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