A chiral SrSi_(2)(srs)superstructure constructed by a dual interaction system showing isotropic electrical conductivity

作     者：Jin Liu Zi-Xiu Lu Fa-Fa Wu Guo-Ling Li Bin Wang Xue-Li Cao Wei Wang Zhu Zhuo Qiao-Hong Li You-Gui Huang Jin Liu;Zi-Xiu Lu;Fa-Fa Wu;Guo-Ling Li;Bin Wang;Xue-Li Cao;Wei Wang;Zhu Zhuo;Qiao-Hong Li;You-Gui Huang

作者机构：CAS Key Laboratory of Design and Assembly of Functional Nanostructuresand Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of SciencesBeijing 100049China Xiamen Key Laboratory of Rare Earth Photoelectric Functional MaterialsXiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China State Key Laboratory of Structure ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of ChinaFuzhou 350108China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2023年第34卷第9期

页      面：317-320页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.21871262 and 21901242) the Natural Science Foundation of Fujian Province(No.2020J05080) the Natural Science Foundation of Xiamen(No.3502Z20206080) Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZR110) the Recruitment Program of Global Youth Experts Youth Innovation Promotion Association CAS(No.2021302) 

主　　题：Electrical conductivity Self-assembly Isotropic π···πInteractions Chiral 

摘      要：Most porous conductive frameworks are highly anisotropic in their structures thus leading to anisotropic charge *** we report a supramolecular self-assembly which is constructed by intermolecular hydrogen bonding andπ···π*** material features a chiral,porous,cubic framework structure withπ-stacked helical columns along all of the three Cartesian *** a result,isotropic charge transport with an electrical conductivity(σ)of 2.1×10^(–7)S/cm is *** achieving isotropic charge transport in aπ-stacked supramolecular assembly,these results provide a new type of isotropic conductive framework materials alternative to conductive metal-organic frameworks(MOFs).