A corrosion-resistant and age-hardenable Mg-Al-Mn-Ca-Ce dilute alloy with fine-grained structure processed by controlled rolling
作者机构:Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and EngineeringNanling CampusJilin UniversityChangchun 130025China State Key Laboratory of Automotive Simulation and ControlJilin UniversityChangchun 130012China International Center of Future ScienceJilin UniversityChangchun 130012China
出 版 物:《Journal of Materials Science & Technology》 (材料科学技术(英文版))
年 卷 期:2023年第163卷第32期
页 面:223-236页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:the National Natural Science Foundation of China(Nos.U19A2084,U22A20109,and 52104376) the China Postdoctoral Science Foundation(Nos.2021T140250 and 2021M701376) Partial financial support came from the Science and Technology Development Program of Jilin Province(Nos.20200201002JC and 20200401025GX)
主 题:Magnesium alloy Micro-alloying Aging G.P.zones Mechanical property Corrosion
摘 要:Low strength and poor corrosion resistance are two long-standing bottlenecks with dilute Mg ***,we report that the corrosion resistance of Mg-0.6Al-0.5Mn-0.2Ca(wt.%)alloy sheet can be significantly improved by micro-alloying with 0.3 wt.%Ce,and the strength can be considerably augmented after aging *** optimization of strength,ductility,and corrosion resistance is difficult due to the inherent trade-off in Mg ***,our aged Mg-0.6Al-0.5Mn-0.2Ca-0.3Ce alloy features with yield strength(YS)of∼194 MPa,ultimate tensile strength(UTS)of∼265 MPa,elongation to failure(EF)of∼17.2%,and corrosion rate(CR)of 2.2 mm y^(−1),the combination of which exhibits competitive advantage over other comparative dilute Mg *** is found that Ce addition decreases the activity of cathodic phases,inhibits detrimental effects of Fe impurities,and forms a protective Ce-containing surface *** high strength stems from the precipitation of ordered Guinier-Preston(G.P.)zones dispersed in uniform fine grains with an average grain size of∼8.2μ*** atomic-scale *** result in a noticeable age hardening response but do not act as crack initiation and propagation site,so our alloy also performs satisfactory *** work sheds light on the design and fabrication of strong,ductile,and corrosion-resistant dilute magnesium alloys to be used in electronic products and automotive bodies.