Dissociation of intra/inter-molecular hydrogen bonds of cellulose molecules in the dissolution process:a mini review
作者机构:Technical Institute of Physics and ChemistryChinese Academy of Sciences29 Zhongguancun East RoadHaidian DistrictBeijing 100190China University of Chinese Academy of SciencesBeijing 100039China College of Chemistry and Chemical EngineeringDezhou UniversityDezhou 253023China
出 版 物:《Journal of Bioresources and Bioproducts》 (生物质资源与工程(英文))
年 卷 期:2016年第1卷第2期
页 面:58-63页
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:supported by the National Natural Science Foundation of China (No.51373191,51172247,51472253) the Chinese Academy of Sciences Visiting Professorships
主 题:Cellulose Dissolution Hydrogen bonds Solvent Ionic liquid
摘 要:Cellulose is abundant in nature,with the advantages of low-cost,biodegradable and biocompatible,low density and high ***,the development and application of cellulose has been lagging behind its potential due to its unique *** has a large quantity of hydroxyl groups which can easily form hydrogen bond *** huge hydrogen bond network makes it extremely difficult to dissolve or melt cellulose,thus limiting the effective use of cellulose *** dissolve cellulose,the key is to break the hydrogen *** article sums up recent studies on the dissociation or breakage of the intramolecular and intermolecular hydrogen bonds in the dissolution of cellulose.