Overview of emerging catalytic materials for electrochemical green ammonia synthesis and process
作者机构：Department of Chemical EngineeringPohang University of Science and Technology(POSTECH)PohangGyeongbukSouth Korea Department of Biological Sciences and BioengineeringInha UniversityIncheonRepublic of Korea
出 版 物：《Carbon Energy》 (碳能源（英文）)
年 卷 期：2023年第5卷第12期
页 面：31-82页
核心收录：
学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）]
基 金：Ministry of Science and ICT South Korea Grant/Award Numbers:2019R1A2C2088174 2021R1A5A1084921
主 题：electrochemical ammonia synthesis hydrogen energy carrier metal-organic-frameworks MXenes single-atom-catalysts
摘 要：The concept of“green-ammonia-zero-carbon emissionis an emerging research topic in the global community and many countries driving toward decarbonizing a diversity of applications dependent on fossil *** light of this,electrochemical nitrogen reduction reaction(ENRR)received great attention at ambient *** low efficiency(%)and ammonia(NH_(3))production rates are two major challenges in making a sustainable ***,hydrogen evolution reaction is another crucial factor for realizing this NH_(3)synthesis to meet the large-scale commercial ***,the(i)importance of NH_(3)as an energy carrier for the next future,(ii)discussion with ENRR theory and the fundamental mechanism,(iii)device configuration and types of electrolytic systems for NH_(3)synthesis including key metrics,(iv)then moving into rising electrocatalysts for ENRR such as single-atom catalysts(SACs),MXenes,and metal–organic frameworks that were scientifically summarized,and(v)finally,the current technical contests and future perceptions are ***,this review aims to give insightful direction and a fresh motivation toward ENRR and the development of advanced electrocatalysts in terms of cost,efficiency,and technologically large scale for the synthesis of green NH_(3).
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