A Cu-based metal-organic framework with two types of connecting nodes as catalyst for oxygen activation

作     者：Zhen Wang Jun-Yu Li Tao Huang Huai-Ming Li Teng Zhang Zhen Wang;Jun-Yu Li;Tao Huang;Huai-Ming Li;Teng Zhang

作者机构：State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2023年第34卷第6期

页      面：463-466页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(No.22005306)for financial support 

主　　题：Copper Metal-organic framework Oxidative C-C coupling Oxygen activation Boronic acids 

摘      要：Using a ditopic organic linker 4-(1H-pyrazol-4-yl)benzoic acid(H_(2)pba),FICN-6,a metal-organic framework containing both Cu_(2)(O_(2)CR)_(4)and Cu_(3)(OH)(pyz)_(3)(O_(2)CR)secondary building units(SBUs),was ***-6 adopts in an unusual intercatenated structure with SBUs from two distinct networks connecting to each *** of Cu_(3)clusters makes FICN-6 a good heterogeneous catalyst for oxygen activation and aerobic oxidative C-C coupling of organic boronic acids.