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Synthesis and Characterization of Aluminum/Carbon Nanotubes Composites: Study of Interfacial Interaction

Synthesis and Characterization of Aluminum/Carbon Nanotubes Composites: Study of Interfacial Interaction

作     者:Mananna Barbeno Pasquale Barone Valentino Pingitore Assunta Bonanno Mariano Davoli FangXu 

作者机构:Physics Department University of Calabria Rende (CS) 87036 Italy Earth Science Department University of Calabria Rende (CS) 87036 Italy 

出 版 物:《Journal of Chemistry and Chemical Engineering》 (化学与化工(英文版))

年 卷 期:2013年第7卷第4期

页      面:313-318页

学科分类:08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 

主  题:Carbon nanotubes aluminum interface structure metal-CNT composite. 

摘      要:Abstract: In this work, the authors present a study of growth and characterization of composite based on AI and CNT (carbon nanotubes. The composites were prepared by a chemical mixing method and characterized by SEM analysis, energy dispersed X-ray measurements, X-ray photoelectron spectroscopy and cathodoluminescence spectroscopy. The analysis showed that the composites are formed by macro-cluster of aluminum oxide on a network of CNT without formation of chemical bonds at interface between particles. The results are compared with those obtained for a sample of CNT with AI traces (〈 0.5%). They show that only the presence of metal traces changes the nanotubes optical properties, with a luminescence signal centered at about 380 nm. These luminescence signals are caused by the adhesion between CNT and AI micro-clusters that promote the formation of band gap with some local energy levels.

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