Electrocatalytic CO_(2) Reduction over Bimetallic Bi-Based Catalysts:A Review

作     者：Wei Chen Yating Wang Yuhang Li Chunzhong Li Wei Chen;Yating Wang;Yuhang Li;Chunzhong Li

作者机构：Key Laboratory for Ultrafine Materials of Ministry of EducationShanghai Engineering Research Center of Hierarchical NanomaterialsFrontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237 School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2023年第5卷第3期

页      面：544-567页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(grant nos.22178104,21838003,and 22008069) the Shanghai Scientific and Technological Innovation Project(grant no.22dz1205900) the Fundamental Research Funds for the Central Universities,and the Shanghai Sailing Program(grant no.20YF1410200). 

主　　题：bimetallic bi-based catalysts CO_(2)reduction electrocatalysis 

摘      要：Electrocatalytic reduction of carbon dioxide(CO_(2))to valuable fuels is an up-and-coming approach.Owing to the low cost,environmental friendliness,and high selectivity to formate single product at low overpotentials,bismuth(Bi)-based catalysts have attracted extensive research attention.In this review,the reaction mechanisms of Bi-based catalysts are first introduced,and the bimetallic Bi-based catalysts synthesized by alloying,doping,and loading strategies are reviewed from the aspects of catalyst component,morphology,synthesis procedure,and performance optimization for electrocatalytic CO_(2)reduction.We provide an in-depth discussion of the existing challenges and an outlook for this highly promising kind of electrocatalysis.