Structure and properties of solid-state synthesized poly(3,4-propylenedioxythiophene)/nano-ZnO composite

作     者：Ahmat Ali Ruxangul Jamal Weiwei shao Adalet Rahman Yakupjan Osman Tursun Abdiryim 

作者机构：Key Laboratory of Petroleum and Gas Fine ChemicalsEducational Ministry of ChinaCollege of Chemistry and Chemical EngineeringXinjiang University Key Laboratory of Functional PolymersXinjiang University 

出 版 物：《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期：2013年第23卷第6期

页      面：524-531页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：the financial support from the National Natural Science Foundation of China(Nos.21064007,21264014) Opening Project of Xinjiang Laboratory of Petroleum and Gas Fine Chemicals(XJDX0908-2011-05) 

主　　题：Poly(3,4-Propylenedioxythiophene) Nano-Zinc oxide Composite Solid-state method 

摘      要：Poly(3,4-propylenedioxythiophene)/nano-Zinic Oxide(PProDOT/ZnO) composites with the content of 3-7 wt%nano-ZnO were synthesized by the solid-state method with FeClas *** structure and morphology of the composites were characterized by Fourier transform infrared(FTIR)spectroscopy,ultraviolet-visible(UV-vis) absorption spectroscopy,X-ray diffraction(XRD) and transmission electron microscopy(TEM).The electrochemical performances of the composites were investigated by galvanostatic charge-discharge,cyclic voltammetry and electrochemical impedance spectroscopy(EIS).The photocatalytic activities of the composites were investigated by the degradation of methylene blue(MB) dyes in aqueous medium under UV light *** results from FTIR and UV-vis spectra showed that the PProDOT/ZnO composites were successfully synthesized by solid-state method,and nano-ZnO had great influences on the conjugation length and oxidation degree of the ***,the PProDOT/5 wt%ZnO had the highest conjugation and oxidation degree among the *** results of XRD analysis indicated that there were some FeCl~- ions as doping agent in the PProDOT matrix,and the content of ZnO had no effect on diffraction pattern of *** studies revealed that the pure PProDOT and composites had similar morphological structure,and all the composites displayed an irregular sponge like *** results of electrochemical tests showed that the PProDOT/5 wt%ZnO had a higher electrochemical activity with a specific capacitance value of 220 F gthan *** results from photocatalytic activities of the composites indicated that the PProDOT/5 wt%ZnO had better photocatalytic activity than other composites.